Showing posts with label Chemistry. Show all posts
Showing posts with label Chemistry. Show all posts

ChemChina takeover of Syngenta

SUBHEAD: For $43billion the Chinese chemical corporation gains control of Swiss Syngenta.

By Michael Shields on 5 May 2017 for Rueters -
(http://uk.reuters.com/article/us-syngenta-ag-m-a-chemchina-idUKKBN1810CU)


Image above: Syngenta corporate logo wall sign. From original article.

ChemChina [CNCC.UL] has won more than enough support from Syngenta shareholders to clinch its $43 billion takeover of the Swiss pesticides and seeds group, the two companies said on Friday.

The deal, announced in February 2016, was prompted by China's desire to use Syngenta's portfolio of top-tier chemicals and patent-protected seeds to improve domestic agricultural output. It is China's biggest foreign takeover to date.

It is one of several deals that are remaking the international market for agricultural chemicals, seeds and fertilisers.

The other deals in the sector are a $130 billion proposed merger of Dow Chemical and DuPont, and Bayer's plan to merge with Monsanto.

The trend toward market consolidation has triggered fears among farmers that the pipeline for new herbicides and pesticides might slow. Regulators have required some divestments as a condition for approving the Syngenta deal.

Based on preliminary numbers, around 80.7 percent of Syngenta shares have been tendered, above the minimum threshold of 67 percent support, the partners said in a joint statement.

The agreed offer is for $465 per share. Syngenta shares closed on Thursday at 459 Swiss francs ($464.5), and rose 0.4 percent in early trade on Friday to 461.20 francs.

The transaction is set to close on May 18 after the start of an additional acceptance period for shareholders and payment of a special 5-franc dividend to holders of Swiss-listed shares on May 16. Holders of U.S.-listed depositor receipts will get the special dividend in July.

Syngenta shares will be delisted from the Swiss bourse and its depository receipts from the New York Stock Exchange.

Chief Executive Erik Fyrwald played down the transition from publicly listed group to becoming part of a Chinese state enterprise, stressing that Syngenta would remain a Swiss-based global company while under Chinese ownership.

"It is very important to understand that this is a financial transaction," he told broadcaster CNBC in an interview.

He saw two major changes: giving Syngenta a long-term shareholder to accompany it during the 12 years it typically takes to discover and launch new products, and helping to overhaul Chinese agriculture, which he called very much behind the global standard.

He said he expected the acceptance rate to easily surpass 90 percent, with a squeeze-out of remaining shareholders to follow if needed in June.

Funding for the acquisition was clear and irrevocable, while refinancing the company after the transaction closed was still being discussed.

"I am very confident we are going to have a strong balance sheet as agreed," he said, with an investment-grade rating that would let it pursue market share growth, investments, capital spending and acquisitions.

Syngenta sells its products in more than 90 countries under such brand names as Acuron, Axial, Beacon and Callisto. It sells seeds such as cereals, corn, rice, soybeans and vegetables.

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Bayer & Syngenta poisoning bees

SUBHEAD: Bayer and Syngenta criticized for secrecy after unpublished research linked high doses of their products to damage to bee colonies.

By Damian Carrington on 22 September 2106 for the Guardian -
(https://www.theguardian.com/environment/2016/sep/22/pesticide-manufacturers-own-tests-reveal-serious-harm-to-honeybees)


Image above: Man spraying barley with Syngenta's thiamethoxam. From (http://wrir4.ucdavis.edu/PHOTOS/CONDUCT/pages/Barley%20thiamethoxam%20ID.htm).

Unpublished field trials by pesticide manufacturers show their products cause serious harm to honeybees at high levels, leading to calls from senior scientists for the companies to end the secrecy which cloaks much of their research.

The research, conducted by Syngenta and Bayer on their neonicotinoid insecticides, were submitted to the US Environmental Protection Agency and obtained by Greenpeace after a freedom of information request.

Neonicotinoids are the world’s most widely used insecticides and there is clear scientific evidence that they harm bees at the levels found in fields, though only a little to date showing the pesticides harm the overall performance of colonies. Neonicotinoids were banned from use on flowering crops in the EU in 2013, despite UK opposition.

Bees and other insects are vital for pollinating three-quarters of the world’s food crops but have been in significant decline, due to the loss of flower-rich habitats, disease and the use of pesticides.

The newly revealed studies show Syngenta’s thiamethoxam and Bayer’s clothianidin seriously harmed colonies at high doses, but did not find significant effects below concentrations of 50 parts per billion (ppb) and 40ppb respectively. Such levels can sometimes be found in fields but concentrations are usually below 10ppb.

However, scientists said all such research should be made public. “Given all the debate about this subject, it is hard to see why the companies don’t make these kinds of studies available,” said Prof Dave Goulson, at the University of Sussex. “It does seem a little shady to do this kind of field study — the very studies the companies say are the most important ones — and then not tell people what they find.”

Prof Christian Krupke, at Purdue University in Indiana, said: “Bayer and Syngenta’s commitment to pollinator health should include publishing these data. This work presents a rich dataset that could greatly benefit the many publicly funded scientists examining the issue worldwide, including avoiding costly and unnecessary duplication of research.”

Ben Stewart, at Greenpeace, said: “If Bayer and Syngenta cared about the future of our pollinators, they would have made the findings public. Instead, they kept quiet about them for months and carried on downplaying nearly every study that questioned the safety of their products. It’s time for these companies to come clean about what they really know.”

Syngenta had told Greenpeace in August that “none of the studies Syngenta has undertaken or commissioned for use by regulatory agencies have shown damages to the health of bee colonies.” Goulson said: “That clearly contradicts their own study.”

Scientists also noted that the companies have been previously been critical of the research methods they themselves used in the new studies, in which bees live in fields but are fed sucrose dosed with neonicotinoids.

In April 2016, in response to an independent study, Syngenta said: “It is important to note that the colony studies were conducted by directly feeding colonies with spiked sucrose, which is not representative of normal field conditions.”

In 2014, commenting on another independent study, Bayer told the Guardian the bees “are essentially force-fed relatively high levels of the pesticide in sugar solutions, rather than allowing them to forage on plants treated with” pesticide.

“If someone had done this type of study and found harm at more realistic levels, the industry would have immediately dismissed it as a rubbish study because it was not what happens naturally to bees,” said Goulson. “So it is interesting that they are doing those kinds of studies themselves and then keeping them quiet.”

Utz Klages, a spokesman for Bayer, said: “The study [Bayer] conducted is an artificial feeding study that intentionally exaggerates the exposure potential because it is designed to calculate a ‘no-effect’ concentration for clothianidin.

lthough the colony was artificially provided with a spiked sugar solution, the bees were allowed to forage freely in the environment, so there is less stress — which can be a contributing variable — than if they were completely confined to cages. Based on these results, we believe the data support the establishment of a no-effect concentration of 20ppb for clothianidin.”

He said a public presentation would be made at the International Congress of Entomology next week in which the new results would be discussed.

A spokesman for Syngenta said: “A sucrose-based mechanism was used on the basis that it was required to expose bees artificially to thiamethoxam to determine what actual level of residue would exert a toxic effect.”

Given the lower concentration usually found in fields, he said: “The reported ‘no adverse effect level’ of 50ppb indicates that honey bee colonies are at low risk from exposure to thiamethoxam in pollen and nectar of seed treated crops. This research is already in the process of being published in a forthcoming journal and is clearly already publicly available through the FOI process in the US.”

Matt Shardlow, chief executive of conservation charity Buglife, said: “These studies may not show an impact on honeybee health [at low levels], but then the studies are not realistic. The bees were not exposed to the neonics that we know are in planting dust, water drunk by bees and wildflowers, wherever neonics are used as seed treatments. This secret evidence highlights the profound weakness of regulatory tests.”

Researchers also note that pollinators in real environments are continually exposed to cocktails of many pesticides, rather than single chemicals for relatively short periods as in regulatory tests.


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Who does what in the soil

SUBHEAD: Part 3 of The Cosmos, the Earth, and Your Health – The Story of Soil.

By Toby Hemenway on 29 August 2016 for Toby Hemenway -
(http://tobyhemenway.com/1404-who-does-what-in-the-soil/)


Image above: Healthy soil can't help but support life. Photo by Jack the Lizard. From (http://www.animal-dino.com/story_of_soil.html).

In the first two episodes of this series on how soil is formed, we’ve been operating at the cosmic level, talking about the how the elements of life were molded during the Big Bang, inside stars, and in explosive supernovae. It’s time to come back to earth, and to reverse scales from the mind-bogglingly large to the infinitesimally small.

When we left our story, the main actors had taken their places on stage; the elements critical for life had formed. Now, as we wait for the curtain to rise, we can look at the playbill to see who these characters are and why they are so beautifully suited for their roles in creating life and building soil.

We can divide the elements of life and soil into two main categories based on how they behave and what roles their structure allows them to play. (I say “in life and soil” because the two are virtually identical: Soil is where most life comes from, and there are almost no elements needed for life that can’t be found in healthy soil.)

The first category is a batch that chemists call “main-group elements” because how they cluster in a large group in the periodic table. The main-group elements involved in soil include carbon, nitrogen, potassium, phosphorus, calcium, magnesium, and sulfur. These are, obviously, major players in story of soil, and copious amounts of all of them get cycled around by living things.

A second group of elements are less abundant in life, but are every bit as crucial in living processes because of their hyperactive, social-butterfly qualities.

They are members of a group that chemists call “transition metals.” That word “transition” hints at the shape-shifting nature of their character that makes them so dynamic and able to play multiple roles in living things.

They include iron, nickel, copper, zinc, manganese, cobalt, and molybdenum. There are many more transition metals, but those seven are the most common and the ones whose roles in life we know best.

I’ll give you some brief biographies of the major players to show what role they fill in life and likewise in soil.

Carbon, that’s a word that’s constantly in the news these days, and often not in a good way. But carbon has been at the center of events long before the fossil-fuel era. It’s hard to conceive of life that isn’t based on carbon.

That’s because it is uniquely multi-functional among all the elements. It comes in several forms; soft graphite, hard diamond, soot, and nanotech inspiring fullerenes are each pure carbon, and each has wildly different qualities from the others.

Carbon can construct nearly 10 million known compounds, vastly more than any other element.

And although a few other elements can bond to one or maybe two others of its kind, only carbon can build chains of itself. When it combines with hydrogen, its most common partner, it forms a tetrahedron, and any Bucky Fuller fans out there know that tetrahedra have almost magical properties.

Water, another molecule with unexpected qualities, also forms a tetrahedron, and that’s food for thought.

Carbon is immensely changeable, depending on what it is linked to. When hydrogen is its principal partner, it forms hydrocarbons. These are liquids such as gasoline, oils and tars, and solids such as plastic. When oxygen is added to the carbon-hydrogen pairing, the result is gums, waxes, fats, sugars, and other gooey substances that we associate with life.

Adding nitrogen yields dyes, amino acids, and alkaloids such as caffeine and psilocybin. Add sulfur, and antibiotics result. Blend in phosphorus and we get DNA and a crucial energy-carrier called ATP.

It’s ability to form innumerable compounds is one reason that carbon plays such a big role in life, but there’s another reason just as powerful: It can store lots of energy when it bonds to itself, and then release that energy when those bonds break. It’s that energy that makes carbon in soil, in the form of organic matter, so important. Just as we do, soil life such as microbes and insects need a constant supply of carbon compounds for their easily available energy.

When the enzymes and acids within living things break carbon bonds, the energy released is transferred to compounds in the organism such as ATP and sugar, moved to places that it is needed, and released again to power more molecule building and unbuilding.

That’s most of what metabolism is: the transfer of energy from carbon compounds, otherwise known as food, from one place to another, to do various important tasks via other carbon compounds such as proteins, DNA, and vitamins that are especially suited to those tasks.

Carbon Compounds Final
Image above: Some of the many forms of carbon. Even if you can’t read chemical structures, you can see that the patterns that carbon creates are many and varied. From original article.

I could write a book on the marvels of carbon (and may some day!) but before carbon’s nuggetized biography takes over this whole article, I will sum up by saying that carbon’s ability to store and move energy, and also to bond with so many other elements and thus shuttle them from place to place, make this element the backbone of life. Soil lacking in carbon—in organic matter and the soil life it breeds—is dead soil, and it creates dead food.

Nitrogen is a much-touted soil nutrient, critical but often so over-emphasized that other nutrients just as valuable get overlooked. It’s needed to build protein, which is found in structural tissues such as muscle and cell membranes, and also in enzymes, active, flexible chains of molecules that are the construction equipment of life.

Enzymes weld together protein, starch, and DNA chains; push needed molecules through cell membranes; repair and regulate DNA, and do essentially all the building, transport, and disassembly that go on within living things. Every living being needs nitrogen to keep protein in good supply.

Nitrogen is also a major ingredient in chlorophyll, the compound that uses sunlight to build sugar out of carbon dioxide in the air. That’s why plants green up so fast when they get a dose of nitrogen. Too much nitrogen can prompt insect damage, because bugs need lots of it and can “smell” when plants have it in overabundance.

Phosphorus stimulates root formation, improves flowering and seed production, strengthens stems and stalks, aids nitrogen-fixing bacteria, and increases disease resistance. It’s used in DNA, special fats that make up cell membranes, and in ATP, which is a principal energy-storing molecule.

Phosphorus is stored in large amounts in seeds as phytin, where it can by used by the developing seedling. Phosphorus also aids in transporting other nutrients around the cell. Some scientists and activists believe we’re rapidly depleting phosphorus supplies and feel that we need to be much better at stewarding it.

Potassium has a role that is less understood, but it is needed for many enzymes to function, and it helps young plants get started, in part by strengthening roots. Potassium-deficient plants are more susceptible to cold, extreme heat, drought, insect predation, and disease.

Calcium is a neglected nutrient that is just beginning to get its due. The textbooks will tell you that calcium is needed in modest amounts to build cell walls, protect against heat stress and disease, aid in nitrogen fixation by bacteria, improve fruit quality, and help in the uptake of other nutrients. That last role conceals a mountain of important and often dismissed functions for calcium.

Maverick soil scientist Dr. William Albrecht was among the first to sniff out calcium’s unsung role in soil biology, nutrition and health, and his work spawned a school of advocates, including the Acres USA publishing team, and soil specialists such as Michael Astera and Steve Solomon. I recommend checking out their work for an expanded and radical view of soil minerals that has helped me immensely in growing nutrient-dense food.

For example, agricultural lime (calcium hydroxide) has been used for millennia to make acidic soils sweeter, that is, to raise their pH. But Albrecht found evidence that it’s the calcium in lime that reverses the nutrient deficiencies that common wisdom claims are due to acid pH. In other words, when soil contains enough calcium, soil acidity matters much less. This is, to put it mildly, controversial, but a view that some serious plant growers swear by.

Calcium also loosens sticky clay soils. So this new school of calcium aficianados recommends much higher levels of calcium in soil than conventional agronomists. They also believe that soil levels of calcium, magnesium, potassium, sodium, iron, zinc, and a few other nutrients should be adjusted to an ideal ratio, roughly 65% calcium,
15% magnesium, 4% potassium, and 1-3% each of the others.

For more on these ratios and the thinking behind them, check out http://soilminerals.com and Michael Astera’s book The Ideal Soil. For an opposing view, see what soil scientist Neal Menzies has to say.

My personal view, and the one that guides my fertilizer recipes, is that most soils benefit from adding more calcium than the conventional guides say, but there is a lot of leeway in the ratio of calcium to other nutrients. I don’t worry about achieving a perfect 65/15/3 balance, just something in the ballpark, or even in the same part of town.

Magnesium is at the center of the chlorophyll molecule, just as iron is at the heart of the very similar hemoglobin molecule in mammals. It’s essential for ferrying phosphorus and iron to where they are needed.

Many of the enzymes that synthesize sugar, fats, and oils contain magnesium. In soil, it increases the stickiness of some clays, so levels that are too high can make soils gummy and even anaerobic. In soils low in clay, adding magnesium sometimes helps soil hold more water and stabilizes organic matter.

To wrap up this segment of our series on soil: Carbon builds structure and stores energy. It’s not properly a nutrient, but its presence in soil in many forms is critical for ecosystem function and everyone’s health.

The elements that make up what soil folk call the primary nutrients are nitrogen, phosphorus, and potassium. Those three are, I think, overemphasized, a legacy of some of the earliest experiments done on plant nutrition that used anything resembling the scientific method.

Justus von Liebig, a brilliant German chemist who made major contributions to organic chemistry and invented important chemical equipment, examined the content of ashes from grains. He found principally nitrogen, phosphorus, and potassium, and since then generations of farmers and soil scientists have concentrated on—and used staggering quantities of—these and only these as nutrients.

The roles of carbon and of the other mineral nutrients were neglected for over a century, leading to depletion of most of the world’s farmable soil and a precipitous decline in nutrition in our food.

The secondary nutrients, calcium and magnesium, are only secondary in sheer mass required, but not in importance to plant, soil, animal, and human health. The same goes for the trace elements. Chalk up another victory for the “quantity over quality” mindset, and a loss for all of life.

I’ve used more words than I expected to get to this point in our tale. We haven’t made it to the trace elements and why those transition metals are so magical and important—so important that some scientists joke that life arose simply as a way to move them around.

We’ll talk about that next time, and begin looking at how to tailor your soil to yield lush amounts of nutrient-dense food: both quantity and quality.

See also:
TobyHemenway: A big Bang for Big Soil 8/9/16
TobyHemenway: The Cosmos, the Earth and Soil 6/22/16

• Toby Hemenway is the author of Gaia’s Garden: A Guide to Home-Scale Permaculture, which was awarded the Nautilus Gold Medal in 2011, was named by the Washington Post as one of the ten best gardening books of 2010, and is the best-selling permaculture book in the world. His new book on urban permaculture, The Permaculture City, was released in July, 2015.


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